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林业科学 ›› 2005, Vol. 41 ›› Issue (5): 106-109.doi: 10.11707/j.1001-7488.20050518

• 论文及研究报告 • 上一篇    下一篇

木材在毛细与非毛细管方向的吸收特征及受液体性质影响的研究

吴洪远 岳斌 沈青   

  1. 东华大学材料科学与工程学院高分子材料系,上海200051
  • 收稿日期:2003-10-09 修回日期:1900-01-01 出版日期:2005-09-25 发布日期:2005-09-25

Absorption of Liquids in Capillary and Non-Capillary of Wood and the Effects of Liquid Properties

Wu Hongyuan,Yue Bin,Shen Qing   

  1. Department of Polymer Materials, College of Material Science and Engineering of Donghua University Shanghai200051
  • Received:2003-10-09 Revised:1900-01-01 Online:2005-09-25 Published:2005-09-25

摘要:

分别应用水、甲酰胺和二碘甲烷3种不同性质的液体,研究木材吸收液体的动力学过程及在毛细管和非毛细管2个方向的不同吸收特征。结果表明:木材吸收液体过程无论在毛细还是非毛细管方向都为三段式进行,其特征是初始和最后阶段为线性吸收,即具有零级动力学吸收的特征;而中间阶段则具有复杂的一级和二级吸收反应动力学的特征。根据吸收现象分析,液体的粘度、极性及Lewis酸碱反应性都将影响木材的吸收过程。根据所记录的动态吸收曲线,文中给出了木材吸收液体的动力学模型及参数。

关键词: 木材, 吸收, 毛细管, 液体

Abstract:

Applying water, formamide and diiodomethane, as probe liquids to penetrate into pine wood at its capillary and non-capillary sections, respectively, the dynamic absorption models of wood had been deduced based on recorded absorption curves. Results showed that wood absorbs liquid in both capillary and non-capillary sections following three steps, I.e. both the initial and final steps followed the zero order adsorption rate, while the bulk step was complexly dominated by a first or second order adsorption rate. Moreover, it was also found that the viscosity, polarity and the Lewis acid-base interactions of liquids were main factors to influence wood absorption.

Key words: wood, absorption, capillary, liquid