欢迎访问林业科学,今天是

林业科学 ›› 2019, Vol. 55 ›› Issue (3): 149-159.doi: 10.11707/j.1001-7488.20190317

• 综合评述 • 上一篇    下一篇

纤维饱和点概念的演变、测试方法及其应用

高鑫1, 周凡1, 庄寿增2, 周永东1   

  1. 1. 中国林业科学研究院木材工业研究所 北京 100091;
    2. 南京林业大学材料科学与工程学院 南京 210037
  • 收稿日期:2017-01-20 修回日期:2017-03-28 出版日期:2019-03-25 发布日期:2019-04-17
  • 基金资助:
    林业公益性行业科研专项(201404502);中央级公益性科研院所专项(CAFYBB2018QA001)。

Concept Evolution, Test Method and Application of Fiber Saturation Point

Gao Xin1, Zhou Fan1, Zhuang Shouzeng2, Zhou Yongdong1   

  1. 1. Research Institute of Wood Industry, CAF Beijing 100091;
    2. College of Material Science and Engineering, Nanjing Forestry University Nanjing 210037
  • Received:2017-01-20 Revised:2017-03-28 Online:2019-03-25 Published:2019-04-17

摘要: 纤维饱和点(FSP)是木材科学中早期提出的概念,距今已超过1个世纪,在木材-水分关系、物理力学性能等木材科学研究各领域均发挥了重要作用。相较于FSP概念的最初形式,其无论从定义形式还是从物理含义等方面都有了变化,从最初以木材内水分状态及其存在位置的定性描述朝着水分与木材结合形式差异、木材内水分势能边界方向发展。目前国内关于FSP的研究相对滞后,也未见系统的FSP测试原理和方法介绍。本研究对FSP概念演变与发展、测试方法及其优缺点进行系统分析,并在此基础上总结FSP在木材-水分关系、木材干燥技术、改性效果评价中的应用及其进一步发展方向。根据木材-水分关系研究的不同阶段,FSP概念可归纳为4种类型:第1类概念强调以物理力学性质转折点及水分存在位置定义FSP;第2类概念以木材细胞壁容纳水分极限作为FSP,简化了限制条件;第3类概念强调水分与木材结合形式差异,从吸、放热的热物理角度等进行阐述;第4类概念引入溶液热力学概念,将FSP视为木材内不同状态水分的相态边界,给出了FSP明确的物理含义。FSP测试方法可归纳为7类,包括外推法、溶剂排出法、压力板法、示差量热法、离心脱水法、核磁共振法和溶液热力学计算法,除外推法、溶液热力学计算法获得的FSP为计算值外,其他方法都可获得细胞壁内吸着水真实含量,测定的FSP明显高于传统引用的FSP平均值30%,但具体应用时应根据实际需求而定。FSP可进一步在木材干缩湿胀特性分析、木材干燥基准制定等方面发挥作用,同时在木材改性效果评价及改性处理后微观构造分析等领域均可应用。在FSP热力学概念基础上衍生的全含水率区间木材-水分关系的化学势表达方式,以及在此基础上发展而来的木材-水分相态图,将成为今后建立木材-水分关系的科学评价体系机制,并进一步服务于科研与生产。

关键词: 纤维饱和点, 木材-水分关系, 概念演变, 测试方法, 应用

Abstract: Fiber saturation point(FSP)is an important concept in the field of wood science which was first proposed by Tiemann in 1906 and has been discussed in the literature for over 100 years. FSP has played an important role in wood-water relations, wood physical and mechanical properties and other research fields in wood science. Despite its importance and extensive study, the exact theoretical definition of the FSP and the correct way to measure the FSP are still debated because considerable progress has been made compared with the initial concept form of FSP. The research on wood-water relations has changed from qualitative description of the state and its locations of water in wood to the direction of water potential differences and water phase boundaries, and relevant new theoretical definitions and test methods of FSP have been presented in recent years. The research on FSP is relatively lagging behind in our country, there are rarely introductions to principles and test methods of FSP. In this paper, the development of FSP concept has been summarized, the advantages and disadvantages of test methods are analyzed systematically. The applications and further developments in wood-water relations, wood drying technology, modification effect are also summarized. According to the different research stages of wood-water relations, the concept of FSP could be divided into 4 types. The first type emphasizes that FSP could be defined from physical and mechanical properties, or locations of water in wood. The second type concept related FSP to the amount of water contained with the water saturated cell wall. The third type concept emphasizes the different combination forms between water and wood, which could result in different thermal phenomenon. The fourth type concept of FSP is based on solution thermodynamics that treats the FSP as a phase boundary, which attaching clear physical meaning to FSP. The test methods of FSP could be divided into 7 types, including extrapolation method, solute exclusion method,pressure plate measurement, differential scanning calorimetry method, centrifugal dehydration method, nuclear magnetic resonance method, and solution thermodynamics calculation method. The actual bound water content in cell wall could be determined from these methods except for extrapolation and solution thermodynamics calculation method. The actual bound water content is obviously higher than 30% which is traditionally considered as average value of FSP. The research on FSP could further play an important role in the analysis of shrinkage and swelling, working out wood drying schedule. It also could be applied in the evaluation of wood modification effect and the microstructure analysis after modification treatment. The chemical potentials expression of the wood-water relationship and wood moisture phase diagram based on the FSP thermodynamic concept would be an important research field of wood-water relations scientific evaluation system, and more attention should be paid in wood science and industry.

Key words: fiber saturation point, wood-water relations, concept evolution, test method, application

中图分类号: