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林业科学 ›› 2024, Vol. 60 ›› Issue (11): 160-169.doi: 10.11707/j.1001-7488.LYKX20230199

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人工林柏木重组木的结构与性能

吴婕妤,吴江源,张亚梅*,于文吉   

  1. 中国林业科学研究院木材工业研究所 北京 100091
  • 收稿日期:2023-05-12 出版日期:2024-11-25 发布日期:2024-11-30
  • 通讯作者: 张亚梅
  • 基金资助:
    高性能重组木连续化制造关键技术与装备(2021YFD2200601)。

Structure and Properties of Scrimber Prepared from Cupressus funebris Plantation Forests

Jieyu Wu,Jiangyuan Wu,Yamei Zhang*,Wenji Yu   

  1. Research Institute of Wood Industry, Chinese Academy of Forestry Beijing 100091
  • Received:2023-05-12 Online:2024-11-25 Published:2024-11-30
  • Contact: Yamei Zhang

摘要:

目的: 采用定向重组技术制备人工林柏木重组木,分析其结构与性能,揭示柏木制备成重组木后性能变化的内因,为人工林柏木高值化利用提供技术参考和理论依据。方法: 制备80%、100%和120%不同压缩率柏木重组木,探究压缩率对重组木耐水性能、力学性能(抗弯性能和水平剪切性能)的影响规律;应用超景深显微镜(UDM)、冷场发射扫描电子显微镜(SEM)、激光共聚焦显微镜(LSM)和透射电镜(TEM)观察重组木微观结构变化以及重组木中胶液分布情况;使用剖面密度测量仪测量垂直于板面表面方向的密度梯度,分析重组木剖面密度。结果: 随着压缩率增大,重组木表面纹理颜色加深,剖面密度逐渐均匀,吸水率(WAR)、吸水厚度膨胀率(TSR)和吸水宽度膨胀率(WSR)逐渐减小,静曲强度(MOR)和水平剪切强度(HSS)逐渐增大。压缩率120%时重组木WAR最小,相比原木降低34.73%,同时重组木MOR和HSS达到最大,分别为125.77和17.05 MPa,相比原木分别提升53.47%和84.32%。剖面密度测量仪、冷场发射扫描电子显微镜、激光共聚焦显微镜和透射电镜观测结果显示,重组木耐水性能和力学性能提升主要是因为随着压缩率增大,木材细胞压缩密实、胶液分布范围更广,在更多的细胞腔和胞间层形成胶合位点,减少吸水时水分进入通道,抑制细胞腔回弹,增强胞间层薄弱结构。结论: 采用定向重组技术将人工林柏木制备成高性能重组木后,其力学性能显著提升;随着压缩率增大,重组木的耐水性能显著增强,压缩率120%时重组木性能达到最优。

关键词: 重组材料, 柏木重组木, 压缩率, 耐水性能, 抗弯性能, 水平剪切性能

Abstract:

Objective: Directional recombinant technology was used to prepare Cupressus funebris scrimber, the structure and performance were analyzed, so as to reveal the internal causes of the performance changes of cypress wood after it is prepared into scrimber, and provide technical references and theoretical basis for the high-value utilization of cypress wood in plantation forests. Method: Different compression rates (80%, 100%, and 120%) were adopted to prepare C. funebris scrimbers, and subsequently the effect of preparation process and compression rates on the water resistance and mechanical properties (bending properties and horizontal shear properties) of C. funebris scrimbers were investigated. Ultra-deep field microscopy (UDM), cold field emission scanning electron microscopy (SEM), laser confocal microscopy (LSM), and transmission electron microscopy (TEM) were used to observe the microstructural changes and glue distribution of scrimber. Also, the vertical profile density of scrimber was studied by profile densitometry. Result: As the compression rates of scrimber increased, the surface color deepened, the profile density more uniform, the water absorption rate (WAR), thickness swelling rate (TSA), and width swelling rate (WSA) gradually decreased, and the modulus of rupture (MOR) and horizontal shear strength (HSS) gradually increased. The WAR of scrimber was the lowest at a compression rate of 120%, which was 34.73% lower than that of C. funebris. The maximum MOR and HSS were 125.77 and 17.05 MPa, respectively, which were 53.47% and 84.32% higher than those of C. funebris. The result of profile density, SEM, LSM, and TEM showed that the improvement of water resistance and mechanical properties of the scrimber was mainly due to the compression denseness of wood cells, the wider distribution of glue, in addition, gluing sites formed by the phenol-formaldehyde resin (PF) among more cells enhanced connections of cell lumen and middle lamella, thus reducing the water entering channels during water absorption, inhibiting the rebound of cell cavities and strengthening the weak structure of middle lamella. Conclusion: The C. funebris can be prepared into scrimber with significantly improved mechanical properties by directional recombination technology, in which water resistance increased with the increase of compression rates. The performance reached the best when the compression rate was 120%.

Key words: reconstituted material, Cupressus funebris scrimber, compression rates, water resistance, bending properties, horizontal shear performance

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