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林业科学 ›› 2009, Vol. 12 ›› Issue (7): 101-105.doi: 10.11707/j.1001-7488.20090717

• 论文 • 上一篇    下一篇

CMC-g-PMMA改性稻壳碎料-水泥复合材料的性能

韩福芹 邵博 王清文 郭垂根 刘一星   

  1. 东北林业大学生物质材料科学与技术教育部重点实验室 哈尔滨150040
  • 收稿日期:2008-04-18 修回日期:1900-01-01 出版日期:2009-07-25 发布日期:2009-07-25
  • 通讯作者: 王清文
  • 基金资助:
     

Properties of Rice Hull Particles-Cement Composites Modified by CMC-g-PMMA

Han Fuqin,Shao Bo,Wang Qingwen,Guo Chuigen,Liu Yixing   

  1. Key Laboratory of Bio-Based Material Science and Technology of Ministry of Education, Northeast Forestry University Harbin 150040
  • Received:2008-04-18 Revised:1900-01-01 Online:2009-07-25 Published:2009-07-25
  • Supported by:
     

摘要:

采用羧甲基纤维素与甲基丙烯酸甲酯的接枝共聚物(CMC-g-PMMA)作为改性剂对稻壳碎料进行表面处理,制成不同稻壳碎料含量的稻壳碎料-水泥复合材料(RHPC)。对RHPC复合材料的密度、抗折性能、断面表面形貌、吸声性能、保温性能和燃烧性能进行测试和分析。结果表明:添加CMC-g-PMMA可大幅度提高RHPC复合材料的抗折强度和模量,当稻壳碎料含量为20%,CMC-g-PMMA添加量为1%时,抗折强度和模量分别为未添加助剂试样的2.27和2.71倍; 声波频率为2 000 Hz以下,提高稻壳碎料含量后,水泥复合材料的吸声系数明显提高,1 000 Hz时,稻壳碎料含量为40%的试样的吸声系数高达0.67; 制备的稻壳碎料-水泥复合材料为不燃性材料,具有良好的保温性能。

关键词: 稻壳碎料, 水泥, 复合材料, 性能

Abstract:

Rice hull particle-cement composites(RHPC)were prepared from rice hull particles treated with the synthesized carboxymethylcellulose methyl methacrylate(CMC-g-PMMA).The density, flexural property, surface topography, acoustics property, thermal insulation and fire retardant property of the RHPC composites were characterized. Results indicated that the samples made from CMC-g-PMMA modified rice hull particles had higher flexural strength and flexural modulus. When the content of rice hull particles was 20% and the content of CMC-g-PMMA was 1%, the value of flexural strength and flexural modulus of the composites changed respectively to 2.27 times and 2.71 times of the value of the sample contained 20% rice hull particles only. The acoustic absorptivity of the samples rose with increasing rice hull particles content when the testing frequency was below 2 000 Hz. The acoustic absorptivity of the samples with 40% rice hull particles was 0.67 at 1 000 Hz. RHPC composites are incombustible and well thermal insulated.

Key words: rice hull particles, cement, composites, properties

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