林业科学 ›› 2022, Vol. 58 ›› Issue (2): 182-195.doi: 10.11707/j.1001-7488.20220218
卢芸1,王慧庆3,骆立1,5,陈粤4,张治国2,*,马星霞1
收稿日期:
2020-10-27
出版日期:
2022-02-25
发布日期:
2022-04-26
通讯作者:
张治国
基金资助:
Yun Lu1,Huiqing Wang3,Li Luo1,5,Yue Chen4,Zhiguo Zhang2,*,Xingxia Ma1
Received:
2020-10-27
Online:
2022-02-25
Published:
2022-04-26
Contact:
Zhiguo Zhang
摘要:
随着现代考古技术迅速发展,被打捞和发掘出的古船日渐增多,对这些脆弱且具有珍贵历史价值的古船进行及时有效保护是重要且必要的。目前,古船保护主要包括清洗、脱盐、脱水定型、修复复原等步骤,同时为进一步增强古船适应现代环境的能力,往往还需进行封护防腐处理。本研究在对古船封护防腐处理技术进行文献梳理的基础上,对比多种封护方法的加固保存效果,总结各封护方法的优缺点。纳米纤维素是性质优良的新型生物纳米材料,在修复糟朽木质文物方面已有所应用,在古船封护加固方面也有探索性研究,纳米纤维素良好的生物相容性和理化性质使其作为古船封护加固材料极具潜力; 特别地,纳米纤维素对古船表面形貌具有更好的保护效果。利用纳米纤维素加固古船,既能提高古船的稳定性,又能最大限度地保证古船原貌不受影响,是一种全新的古船加固思路。随着当前文保科技化的快速发展,在古船封护防护领域,今后应该: 1)深入探究桐油、生漆等天然传统封护原料的改性规律和工艺创新,聚焦纳米纤维素对其性能的提升作用; 2)开发研究古船的抗菌防霉防护处理,提升生物抗性的同时维持古船原貌,且对环境无负面影响; 3)重视古船中Fe3+对木材的危害,系统研究纳米纤维素对不同加固处理基材的封护表现并进行全面评估。
中图分类号:
卢芸,王慧庆,骆立,陈粤,张治国,马星霞. 古船封护防腐处理技术进展及纳米纤维素应用前景探讨[J]. 林业科学, 2022, 58(2): 182-195.
Yun Lu,Huiqing Wang,Li Luo,Yue Chen,Zhiguo Zhang,Xingxia Ma. The State of Art of the Archaeological Wood Ships Finishing and Nanocellulose Related Applications[J]. Scientia Silvae Sinicae, 2022, 58(2): 182-195.
表2
封护液成分及效果"
分组 Group | 封护液成分 Element of protective agent | 封护效果 Effect of protective agent |
A | 羟丙基纤维素/纤维素纳米晶体 HPC/CNC | 表面覆膜情况好、封护薄膜最致密均匀、薄膜覆盖面积和厚度略大、木材硬度大幅增强、水接触角提升 Good surface property of cover film, most dense and uniform effect of protective film, slightly film coverage area and thickness, greatly enhanced hardness of wood and raised water contact angle |
B | 羧甲基纤维素/ TEMPO氧化纳米纤维 CMC/TEMPO TO-NFC | 薄膜覆盖面积和厚度略大、封护后色差最小、水接触角提升、耐磨性好Slightly larger film coverage area and thickness, minimum color difference after liquid sealing, raised water contact angle and excellent wearability |
C | 羟乙基纤维素/纤维素纳米晶体 HEC/CNC | 表面覆膜情况好、封护薄膜较致密均匀、木材硬度大幅增强、水接触角提升、耐磨性好 Good surface property of cover film, better dense and uniform effect of protective film, enhanced hardness of wood, raised water contact angle and excellent wearability |
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