欢迎访问林业科学,今天是

林业科学 ›› 2022, Vol. 58 ›› Issue (2): 182-195.doi: 10.11707/j.1001-7488.20220218

• 综合评述 • 上一篇    下一篇

古船封护防腐处理技术进展及纳米纤维素应用前景探讨

卢芸1,王慧庆3,骆立1,5,陈粤4,张治国2,*,马星霞1   

  1. 1. 中国林业科学研究院木材工业研究所 北京 100091
    2. 国家文物局考古研究中心 北京 100013
    3. 合肥工业大学化学与 化工学院高分子系 合肥 230009
    4. 广州市白云文物保护工程有限公司 广州 510540
    5. 北京林业大学材料科学与技术学院 北京 100083
  • 收稿日期:2020-10-27 出版日期:2022-02-25 发布日期:2022-04-26
  • 通讯作者: 张治国
  • 基金资助:
    中央公益性科研院所基本科研业务费专项资金项目(CAFYBB2019ZB008);中央公益性科研院所基本科研业务费专项资金项目(CAFYBB2020QB005);国家自然科学基金项目(31870535);国家自然科学基金项目(32122058)

The State of Art of the Archaeological Wood Ships Finishing and Nanocellulose Related Applications

Yun Lu1,Huiqing Wang3,Li Luo1,5,Yue Chen4,Zhiguo Zhang2,*,Xingxia Ma1   

  1. 1. Research Institute of Wood Industry, Chinese Academy of Forestry Beijing 100091
    2. National Center of Archaeology Beijing 100013
    3. Department of Polymer, School of Chemistry and Chemical Engineering, Hefei University of Technology Hefei 230009
    4. Guangzhou Baiyun Cultural Relics Protection Engineering Co., Ltd Guangzhou 510540
    5. College of Material Science and Technology, Beijing Forestry University Beijing 100083
  • Received:2020-10-27 Online:2022-02-25 Published:2022-04-26
  • Contact: Zhiguo Zhang

摘要:

随着现代考古技术迅速发展,被打捞和发掘出的古船日渐增多,对这些脆弱且具有珍贵历史价值的古船进行及时有效保护是重要且必要的。目前,古船保护主要包括清洗、脱盐、脱水定型、修复复原等步骤,同时为进一步增强古船适应现代环境的能力,往往还需进行封护防腐处理。本研究在对古船封护防腐处理技术进行文献梳理的基础上,对比多种封护方法的加固保存效果,总结各封护方法的优缺点。纳米纤维素是性质优良的新型生物纳米材料,在修复糟朽木质文物方面已有所应用,在古船封护加固方面也有探索性研究,纳米纤维素良好的生物相容性和理化性质使其作为古船封护加固材料极具潜力; 特别地,纳米纤维素对古船表面形貌具有更好的保护效果。利用纳米纤维素加固古船,既能提高古船的稳定性,又能最大限度地保证古船原貌不受影响,是一种全新的古船加固思路。随着当前文保科技化的快速发展,在古船封护防护领域,今后应该: 1)深入探究桐油、生漆等天然传统封护原料的改性规律和工艺创新,聚焦纳米纤维素对其性能的提升作用; 2)开发研究古船的抗菌防霉防护处理,提升生物抗性的同时维持古船原貌,且对环境无负面影响; 3)重视古船中Fe3+对木材的危害,系统研究纳米纤维素对不同加固处理基材的封护表现并进行全面评估。

关键词: 考古木材, 古船, 木材封护, 饱水木材, 木材防腐, 纳米纤维素

Abstract:

With the continuous development of archaeological technology in modern society, the number of ancient ships excavated is increasing gradually. It is important and necessary to conserve these archaeological wood artifacts timely and effectively, which are precious records of human civilization. To promote proactively the development of ancient ship conservation technology, there is a growing trend to constantly seek excellent wood finishing materials, and explore more effective and efficient wood finishing method in the practice, thereby trying to protect the important information like runes or artistic ornamentation carried by ancient ships and to avoid damaging human historical resources. At present, many wood finishing materials or method have been applied to the reinforcement and conservation of ancient ships. Under this situation, by sorting out the relevant literature of traditional and conventional method, the main aim of this study is to summarize the merits and demerits of various wood finishing method, after comparing with finishing effect. Nanocellulose, a unique and promising natural material extracted from native cellulose, has gained much attention for its utilization as an archaeological wood finishing material. At present, nanocellulose has been applied in the restoration and conservation of archaeological wood artifacts. Furthermore, there have been some exploratory studies on the finishing and reinforcement of ancient ships. Nanocellulose is a good candidate for finishing and strengthening materials of ancient ships, because of its remarkable physical properties, special surface chemistry and excellent biodegradability. Particularly, owing to working wonderfully on the wood surface, the effects of nanocellulose remaining the original appearances of ancient ships are extremely prominent. Thus, using nanocellulose to strengthen and conserve ancient ships can not only improve their stability but also remain the original appearances as much as possible, which provide a new approach to strengthen ancient ships. Nowadays, with the rapid technological development of heritage conservation, there are many research aspects about ancient ships finishing needing to be developed in the future: 1) In-depth study of the anti-oxidation, anti-corrosion and moth-proof mechanisms of the traditional treatments such as tung oil coating and lacquer coating to reveal the interactions between tung oil and urushiol polymer and the chemical components of the cell wall, and further explore the modification and technological innovation of traditional natural finishing materials. 2) The development of the anti-bacterial and anti-mildew protection of ancient wooden ships, to enhance the adaptation of ancient ships to exhibition environments. The water-soluble protective agent is urgently needed to improve the biological resistance of the ancient ships. 3) The cutting-edge research result of nanocellulose are highly inspired to ancient wood finishing. The systematical study on the sealing performances and the long-term stability of nanocellulose on different reinforced wooden substrates is needed to comprehensively evaluate the role of nanocellulose in wood coating. Especially the performance improvement of nanocellulose-modified traditional materials, such as tung oil and raw lacquer, on mechanical properties, weather resistance and pollution resistance should be focused on, and the novel necessary function of nanocellulose-based wood finishing materials, like capturing the abundant Fe3+ in ancient wooden ships might be futher developed. Thus, the development of nanocellulose in wood cultural relics protection should be expanded.

Key words: archaeological wood, ancient ships, wood finishing, waterlogged wood, wood preservation, nanocellulose

中图分类号: