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林业科学 ›› 2009, Vol. 12 ›› Issue (9): 106-110.doi: 10.11707/j.1001-7488.20090918

• 论文 • 上一篇    下一篇

沙蒿木蠹蛾性诱剂的分析合成与生物活性

张金桐1 骆有庆2 宗世祥2 李占文3   

  1. 1. 山西农业大学文理学院 太谷 030801; 2. 北京林业大学林学院 北京 100083; 3. 宁夏灵武市森林病虫害防治站 灵武 750001
  • 收稿日期:2009-01-15 修回日期:1900-01-01 出版日期:2009-09-25 发布日期:2009-09-25
  • 基金资助:
     

Analysis,Synthesis and Biological Activities of Sex Attractant forHolcocerus artemisiae (Lepidoptera: Cossidae)

Zhang Jintong1,Luo Youqing2,Zong Shixiang2,Li Zhanwen3   

  1. 1. College of Art and Science, Shanxi Agricultural University Taigu 030801; 2. Forest College, Beijing Forestry UniversityBeijing 100083;3. Lingwu Station of Forest Diseases and Pests Control of Ningxia Lingwu 750001
  • Received:2009-01-15 Revised:1900-01-01 Online:2009-09-25 Published:2009-09-25
  • Supported by:
     

摘要:

采用毛细管气相色谱(GC)和触角电位测定(EAG)技术分析沙蒿木蠹蛾雌蛾性信息素腺体提取物。结果表明:在提取物中存在有顺-5-十二碳烯乙酸酯 (Z5-12∶ Ac)、顺-5-十四碳烯乙酸酯 (Z5-14∶Ac)和顺-5-十二碳烯-1-醇 (Z5-12∶OH) 3种主要成分。通过人工合成得到相应的标准化合物,林间诱蛾试验结果显示: Z5-12∶Ac和Z5-14∶Ac 2种组分的组合具有很高的诱蛾活性,且具有专一性,当加入反-3-顺-5-十二碳二烯乙酸酯 (E3,Z5-12∶Ac) 时诱蛾活性增加。将3种化合物按10∶6∶0.5配成性诱剂制成诱芯(825 μg·个-1),诱蛾效果最佳, 日平均诱蛾7.2头。此性诱剂可用以田间诱捕和虫情监测,为沙蒿木蠹蛾的综合防治提供一条新的方法和技术。

关键词: 沙蒿木蠹蛾, 性诱剂, 化学合成, 生物活性

Abstract:

The female sex pheromone gland extract of Holcocerus Artemisiae was separated and indentified by gas spectrometry (GC) and electroantennograms (EAG). The result indicated that (Z)-5-dodecenyl acetate (Z5-12∶ Ac), (Z)-5-tetradecenyl acetate (Z5-14∶ Ac) and (Z)-5-dodecen-1-ol (Z5-12∶ OH) the major pheromone components. These chemicals were artificially synthesized. Results of field trials showed that the mixture of Z5-12∶ Ac and Z5-14∶ Ac had high biological activity and specificity. The addition of (E, Z)-3,5-dodecadicen-1-yl acetate (E3,Z5-12∶ Ac) to the mixture increased attractive. The traps baited with rubber septa impregnated with Z5-12∶ Ac, Z5-14∶ Ac and E3, Z5-14∶ Ac in a 10∶6∶0.5 ratio were the most effective. On an average, 7.2 male moths were caught by a trap baited with 825 μg of the sex attractant per day. The sex attractant can be used for trapping the male and for the insect survey, which would provides a new method and technique for the integrated control of H. artemisiae.

Key words: Holcocerus artemisiae, sex attractant, synthesis, biological activity

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