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林业科学 ›› 2011, Vol. 47 ›› Issue (9): 108-113.doi: 10.11707/j.1001-7488.20110918

• 论文 • 上一篇    下一篇

纳米Al2O3 改性水性木器漆耐磨性和硬度的研究

龙玲1, 万祥龙2, 曲岩春1   

  1. 1. 中国林业科学研究院木材工业研究所 国家林业局木材科学与技术重点实验室 北京 100091;2. 德国明斯特大学物理化学研究所和纳米技术中心 威斯特法伦州 48149
  • 收稿日期:2009-11-25 修回日期:2010-07-08 出版日期:2011-09-25 发布日期:2011-09-25

Study on Wearing Resistance and Hardness of the Nano-Al2O3 Modified Waterborne Wood Coating

Long Ling1, Wan Xianglong2, Qu Yanchun1   

  1. 1. Key Lab. of Wood Science and Technology of State Forestry Administration Research Institute of Wood Industry,CAF Beijing 100091;2. Institute of Physical Chemistry and Center of Nanotechnology University of Münster Westfälische Wilhelms 48149
  • Received:2009-11-25 Revised:2010-07-08 Online:2011-09-25 Published:2011-09-25

摘要:

为提高水性聚丙烯酸酯木器漆的耐磨性和硬度,进行纳米Al2O3浆料的制备及其对水性木器漆改性的研究,探讨分析 不同制备方法和Al2O3添加量对漆膜耐磨性和硬度的影响。结果表明: 以聚丙烯酰胺为分散剂、聚乙二醇和辛基酚聚氧乙烯醚为润湿剂、聚乙烯吡咯烷酮为稳定保护胶,在高速搅拌下制成的纳米Al2O3浆料,在透射电镜下观察发现纳米Al2O3颗粒分布均匀,具有良好的分散性; 在不影响漆膜透明度的情况下,漆膜耐磨性和硬度随Al2O3添加量增加得到提高,添加量在1.5%时漆膜具有较好的耐磨性和硬度; 纳米杂合工艺法的漆膜耐磨性和硬度优于后添加法制备的水性木器漆涂膜。

关键词: 纳米Al2O3, 水性木器漆, 浆料, 耐磨性能, 漆膜硬度

Abstract:

The preparation of nano-Al2O3 slurry and modified waterborne wood coating with nano-Al2O3 slurry were studied in this paper to improve the wearing resistance and hardness of the polyacrylate coating on the surface of wood. The effects of the preparative technique and the contents of nano-Al2O3 on wearing resistance and hardness were discussed. The results showed that nano-Al2O3 slurry, which was prepared with polyacrylamide, polyglycol, polyoxyethylene octyl phenyl ether and protective colloid by bead mill and ultrasonic device, stored stably and was suitable for the system of waterborne coating. The slurry had good dispensability and Al2O3 kept in nano size observed by TEM. The films have good wearing resistance and hardness when Al2O3 content reach 1.5% without change the transparence by additive. The wearing resistance and hardness of the hybrid films were better than that of the films mixed with nano additive.

Key words: nano-Al2O3, waterborne wood coating, slurry, wearing resistance, hardness of film

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