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林业科学 ›› 2009, Vol. 12 ›› Issue (6): 121-126.doi: 10.11707/j.1001-7488.20090621

• 论文 • 上一篇    下一篇

木材乳液胶黏剂用复合变性玉米淀粉乳液

时君友1,2,3顾继友2, 王3   

  1. (北华大学 吉林 132013; 东北林业大学 哈尔滨 150040; 清华大学化学工程系 北京 100084)
  • 收稿日期:2007-08-27 修回日期:1900-01-01 出版日期:2009-06-25 发布日期:2009-06-25

Composite Modified Starch Emulsion for WoodLatex Adhesives

Shi Junyou1,2,3,Gu Jiyou2,Wang Yao3   

  1. (Beihua University Jilin 132013; Northeast Forestry University Harbin 150040; Department of Chemical Engineering of Tsinghua University Beijing 100084)
  • Received:2007-08-27 Revised:1900-01-01 Online:2009-06-25 Published:2009-06-25

摘要:

将玉米淀粉酸解氧化后,采用过硫酸铵为引发剂,与丙烯酸胺接枝共聚,得到复合改性淀粉。通过考察各因素对接枝共聚产物接枝百分率和接枝效率的影响,确定接枝共聚反应的条件为:接枝反应温度50 ℃; 反应时间3 h; 淀粉与丙烯酰胺质量比0.8。通过对复合变性淀粉工艺条件的验证性试验及其的理化性能分析,证明复合变性淀粉适于制备乳液胶黏剂。

关键词: 酸解氧化玉米淀粉, 接枝共聚, 性能表征

Abstract:

The corn starch was acidthinned and oxidized,then grafted copolymerization acrylamide,so composite modified starch is synthesized. By examining the effect of each element on G(grafting percentage) and GE(grafting effection) of graft copolymerization production,the condition of graft copolymerization reaction were determined:50 ℃ of graft reaction temperature,3 h of reaction time,0.8 of the mass ratio of starch to acrylamide. By validating test of technology condition for composite modified starch and analysis on its physical and chemical properties,composite modified starch suitable for preparing wood adhesive was testified.

Key words: acidthinned and oxidized corn starch, grafting copolymerization, characterization