古建筑木构件有机型防腐防虫剂制备及其效果

doi:10.11707/j.1001-7488.20210817

Abstract

Abstract:

Objective: In order to satisfy the prevention and control needs of different biological hazards of ancient building wooden components, a kind of water-based organic preservatives were planned to be developed. Method: A series of preservatives were developed by the combination of propiconazole, 1, 2-benzoisothiazolin-3-ketone (BIT) and lambda-cyhalothrin with an excellent anticorrosion effect. The stability of the preservatives and the anti-erosion performances of treated wood were tested, and the anti-corrosion effects of the preparation were comprehensively evaluated by means of laboratory anti-corrosion test and field fast anti-pest test. Result: After diluted 250 times with water, the microemulsions were kept translucent for more than 60 days. These microemulsions were not freeze at-25℃ overnight. The fixation rate of the effective components of the medicament was over 90%. The fixation rate of chemicals in wood was related to their solubility in water. The component with high solubility had a low fixation rate. The appearance color of treated wood was almost unchanged. The result of indoor corrosion resistance test showed that the wood mass loss rate was less than 5% under the condition above 161.3 g·m^-3 (propiconazole/lambda-cyhalothrin=20:1). The test result of termite control in the field showed that under the condition of drug loading of 134.8 g·m^-3 (propiconazole/lambda-cyhalothrin=20:1), the anti-corrosion performance was 10, and the anti-termite performance could reach 10, and the anti-termite performance of untreated wood was 5.8. Conclusion: Water-based organic preservatives were developed, which could adjust the proportion of effective ingredients flexibly according to the different needs of the actual biological hazard control of ancient buildings. The microemulsion contained propiconazole, BIT and lambda-cyhalothrin, and had effective component content of more than 10%. The microemulsion not only showed stable performances but also had a high fixation rate of its active component in wood, so it had good anti-corrosion and anti-insect effect.

Key words: preservative and insect repellent, organically, microemulsion, ancient buildings wood, wood biodeterioration

CLC Number:

S782.33

Bin Zhang,Xingxia Ma,Mingliang Jiang,Xiaowen Li. Preparation and Effect Evaluation of Organic Preservative for Ancient Buildings Wood Biodeterioration[J]. Scientia Silvae Sinicae, 2021, 57(8): 167-175.

Figures/Tables 11

Table 1

Fig.1

Table 2

Table 3

Fig.2

Table 4

Table 5

Fig.3

Table 6

Fig.4

Table 7

References 0

	陈允适. 古建筑木结构与木质文物保护. 北京: 中国建筑工业出版社, 2007.
	Chen Y S . Protection of wooden structure of ancient buildings and cultural relics. Beijing: China Construction Industry Press, 2007.
	方晓航, 仇荣亮. 农药在土壤环境中的行为研究. 环境与土壤, 2002, 11 (1): 94- 97.
	Fang X H , Qiu R L . Study on the behavior of pesticides in soil environment. Environment and Soil, 2002, 11 (1): 94- 97.
	国家药典委员会. 中华人民共和国药典. 北京: 中国医药科技出版社, 2020.
	State Pharmacopeia Committee of China . Pharmacopoeia of the People's Republic of China. Beijing: China Medical Science and Technology Press, 2020.
	华乃震. 农药制剂的进展和动向(上). 农药, 2008a, 47 (2): 79- 81, 89.
	Hua N Z . Advance and trend of pesticide formulation development. Agrochemicals, 2008a, 47 (2): 79- 81, 89.
	华乃震. 农药制剂的进展和动向(中). 农药, 2008b, 47 (3): 157- 160, 163.
	Hua N Z . Advance and trend of pesticide formulation development. Agrochemicals, 2008b, 47 (3): 157- 160, 163.
	华乃震. 农药制剂的进展和动向(下). 农药, 2008c, 47 (4): 235- 239, 247.
	Hua N Z . Advance and trend of pesticide formulation development. Agrochemicals, 2008c, 47 (4): 235- 239, 247.
	华乃震. 农药微乳剂的研究和进展. 现代农药, 2004, 3 (5): 19- 23. doi: 10.3969/j.issn.1671-5284.2004.05.007
	Hua N Z . Research and development of pesticide microemulsion. Modern Agrochemicals, 2004, 3 (5): 19- 23. doi: 10.3969/j.issn.1671-5284.2004.05.007
	蒋明亮. 铜防腐剂及百菌清处理3种木材的野外耐久性能. 木材工业, 2006, 20 (5): 11- 13. doi: 10.3969/j.issn.1001-8654.2006.05.004
	Jiang M L . Durability of 3 wood species treated with copper based preservative and chlorothalonil. China Wood Industry, 2006, 20 (5): 11- 13. doi: 10.3969/j.issn.1001-8654.2006.05.004
	李扬, 李梦耀, 袁胜, 等. 五氯酚钠在黄土性土壤中的吸附与解吸. 应用化工, 2014, 43 (5): 880- 886.
	Li Y , Li M Y , Yuan S , et al. Adsorption and desorption of sodium pentachlorophenol in the loessial soil. Applied Chemical Industry, 2014, 43 (5): 880- 886.
	李晓文, 马星霞, 蒋明亮. 戊唑醇和丙环唑的耐腐性能评价. 木材工业, 2011, 25 (5): 13- 15. doi: 10.3969/j.issn.1001-8654.2011.05.004
	Li X W , Ma X X , Jiang M L . Decay resistance of triazole wood preservatives containing tebuconazole and propiconazole. China Wood Industry, 2011, 25 (5): 13- 15. doi: 10.3969/j.issn.1001-8654.2011.05.004
	李晓文, 蒋明亮. 三唑杀菌剂在木材保护中的应用和发展展望. 林业科技通讯, 2016, (12): 61- 65.
	Li X W , Jiang M L . A review on the studies about triazole fungicides applied in wood preservatives. Forest Science and Technology, 2016, (12): 61- 65.
	林徽因. 中国建筑常识. 北京: 北京理工大学出版社, 2017.
	Lin H Y . Common sense of Chinese architecture. Beijing: Beijing University of Technology Press, 2017.
	马星霞, 蒋明亮, 王洁瑛. 气候变暖对中国木材腐朽及白蚁危害区域边界的影响. 林业科学, 2015, 51 (11): 83- 90.
	Ma X X , Jiang M L , Wang J Y . The climate change effects on boundaries of wood decay and termite hazard zones in China. Scientia Silvae Sinicae, 2015, 51 (11): 83- 90.
	马星霞, 王洁瑛, 蒋明亮, 等. 中国陆地木材生物危害等级的区域划分. 林业科学, 2011, 47 (12): 129- 135. doi: 10.11707/j.1001-7488.20111219
	Ma X X , Wang J Y , Jiang M L , et al. Biological hazard classifications and hazard map development for terrestrial applications of wood in China. Scientia Silvae Sinicae, 2011, 47 (12): 129- 135. doi: 10.11707/j.1001-7488.20111219
	马星霞, 王麟, 朱海燕, 等. 全国木结构古建筑木蜂危害风险区域划分. 林业科学, 2021, 57 (4): 116- 123.
	Ma X X , Wang L , Zhu H Y , et al. The risk zones of carpenter bees Xylocopa for wooden structure of ancient buildings in China. Scientia Silvae Sinicae, 2021, 57 (4): 116- 123.
	马星霞, 张斌, 蒋明亮, 等. 2020. 一种防治古建筑木构件生物败坏的水基化药剂. CN202010098095.0.
	Ma X X, Zhang B, Jiang M L, et al. 2020. A kind of water based medicament for preventing and controlling the biological damage of ancient building wood components. CN202010098095.0. [in Chinese]
	倪洁, 张丽丽, 程康华. 水载型复合木材防腐剂的制备及其抑菌性能. 东北林业大学学报, 2016, 44 (10): 91- 97. doi: 10.3969/j.issn.1000-5382.2016.10.019
	Ni J , Zhang L L , Cheng K H . Preparation and antimicrobial activities of water-borne composite wood preservative. Journal of Northeast Forestry University, 2016, 44 (10): 91- 97. doi: 10.3969/j.issn.1000-5382.2016.10.019
	倪越, 严万春, 耿金懿, 等. 新工业防霉杀菌剂1, 2-苯并异噻唑啉-3-酮的研制. 精细与专用化学品, 2004, 12 (20): 21- 22. doi: 10.3969/j.issn.1008-1100.2004.20.008
	Ni Y , Yan W C , Geng J Y , et al. Preparation of new industrial anti-mildew bactericide: 1, 2-benzisothiazdin-3-one. Fine and Specialty Chemicals, 2004, 12 (20): 21- 22. doi: 10.3969/j.issn.1008-1100.2004.20.008
	沈佳颖, 于振洋, 尹大强, 等. 林丹通过MAPK和UPR通路与干扰线粒体功能诱导黑腹果蝇(Drosophila melanogaster)肿瘤细胞迁移. 生态毒理学报, 2018, 13 (5): 97- 109.
	Shen J Y , Yu Z Y , Yin D Q , et al. Tumor cell migration of Drosophila melanogaster by lindane exposure with involvement of MAPK and UPR pathways and mitochondrial dysfunction. Asian Journal of Ecotoxicology, 2018, 13 (5): 97- 109.
	史梦竹, 李建宇, 傅建炜, 等. 8%高效氯氟氰菊酯微乳剂对环境生物的安全性评价. 生物安全学报, 2014, 23 (1): 51- 55. doi: 10.3969/j.issn.2095-1787.2014.01.010
	Shi M Z , Li J Y , Fu J W , et al. Safety evaluation of 8% lambda-cyhalothrin on environmental organisms. Journal of Biosafety, 2014, 23 (1): 51- 55. doi: 10.3969/j.issn.2095-1787.2014.01.010
	汤方, 崔荔, 唐进根. 黑翅土白蚁和黑胸散白蚁对药剂传毒效率的差异. 南京林业大学学报: 自然科学版, 2007, 31 (6): 69- 72. doi: 10.3969/j.issn.1000-2006.2007.06.016
	Tang F , Cui L , Tang J G . Difference in transmission efficiency to pesicides between Odontotermes formosanus (Shirki) and Reticulitermes Chinensis (Snyder). Journal of Nanjing Forestry University: Natural Sciences Edition, 2007, 31 (6): 69- 72. doi: 10.3969/j.issn.1000-2006.2007.06.016
	席丽霞, 蒋明亮, 马星霞. 三唑制剂及其铜唑制剂处理材的防腐性能. 木材工业, 2015, 29 (3): 14- 17.
	Xi L X , Jiang M L , Ma X X . Decay resistance of wood treated with triazole and copper triazole preservatives. China Wood Industry, 2015, 29 (3): 14- 17.
	席丽霞, 蒋明亮. 三唑类木材防腐剂研究进展. 林产工业, 2013, 40 (4): 3- 8. doi: 10.3969/j.issn.1001-5299.2013.04.001
	Xi L X , Jiang M L . Review on the research progress of triazole wood preservatives. China Forest Products Industry, 2013, 40 (4): 3- 8. doi: 10.3969/j.issn.1001-5299.2013.04.001
	谢国红, 陈锡岭, 闫清华. 阳离子表面活性剂对五氯酚钠在土壤中吸附的影响. 农业系统科学与综合研究, 2005, 21 (3): 193- 195. doi: 10.3969/j.issn.1001-0068.2005.03.009
	Xie G H , Chen X L , Yan Q H . Adsorption of sodium pentachlorophenate in soil with cation surfactant-bromide hexadecyltrimethyl-ammonium. System Sciences and Comprehensive Studies in Agriculture, 2005, 21 (3): 193- 195. doi: 10.3969/j.issn.1001-0068.2005.03.009
	易欣, 于伸, 李延南. 中国传统木结构建筑的色彩应用研究. 华中建筑文化, 2012, 31 (2): 131- 134.
	Yi X , Yu S , Li Y N . Research on color application in Chinese traditional timberwork building. Huazhong Architecture, 2012, 31 (2): 131- 134.
	张飞龙, 赵晔. 中国史前漆器文化源与流——中国史前生漆文化研究. 中国生漆, 2014, (2): 1- 7. doi: 10.3969/j.issn.1000-7067.2014.02.001
	Zhang F L , Zhao Y . The source and flow of Chinese prehistoric lacquer culture—study on the culture of raw lacquer before Chinese history. China Lacquer, 2014, (2): 1- 7. doi: 10.3969/j.issn.1000-7067.2014.02.001
	Benarbia M A , Macherel D , Faure S , et al. Plasmatic concentration of organochlorine lindane acts as metabolic disruptors in HepG2 liver cell line by inducing mitochondrial disorder. Toxicology & Applied Pharmacology, 2013, 272 (2): 325- 334.
	Croom E L , Shafer T J , Evans M V , et al. Improving in vitro to in vivo extrapolation by incorporating toxicokinetic measurements: a case study of lindane-induced neurotoxicity. Toxicology & Applied Pharmacology, 2015, 283 (1): 9- 19.
	Khezri A , Lindeman B , Krogen S A K , et al. Maternal exposure to a mixture of persistent organic pollutants (POPs) affects testis histology, epididymal sperm count and induces sperm DNA fragmentation in mice. Toxicology & Applied Pharmacology, 2017, 329, 301- 308.
	Liu M , Zhong H , Ma E N , et al. Resistance to fungal decay of paraffin wax emulsion/copper azole compound system treated wood. International Biodeterioration & Biodegradation, 2018, 129, 61- 66.
	Jones A S , Marini J , Solo-Gabriele H M , et al. Arsenic, copper, and chromium from treated wood products in the US disposal sector. Waste Management, 2019, 87, 731- 740. doi: 10.1016/j.wasman.2019.03.004

编号 No.	有效成分含量Content of effective components(%)
编号 No.	丙环唑Pro.	BIT	高效氯氟氰菊酯Cyh.
1	8	2	0.5
2	5	5	1
3	10	0	0.5
4	4	6	0

有效成分 Effective component	热贮前质量分数 Mass concentration before thermal storage(%)	热贮后质量分数 Mass concentration after thermal storage(%)	降解率 Degradation rate(%)
丙环唑Pro.	5.11	4.95	3.22
BIT	5.06	4.82	5.15
高效氯氟氰菊酯Cyh.	1.04	1.04	0.32
总计/平均Total/mean	11.21	10.82	3.57

菌种 Fungus	微乳剂1 No.1 microemulsion			微乳剂2 No.2 microemulsion			微乳剂4 No.4 microemulsion
菌种 Fungus	800×	400×	200×	500×	250×	125×	400×	200×	100×
密粘褶菌 Gloeophyllum trabeum	44.02	51.61	57.19	45.31	49.76	58.94	42.99	55.31	58.61
彩绒革盖菌 Coriolus versicolor	31.91	36.50	42.10	34.02	37.74	45.03	30.19	40.25	47.08
曲霉Aspergillus sp.	19.36	22.53	24.18	16.75	19.43	20.49	16.42	18.92	21.58
可可球二孢 Botryodiplodia theobromae	17.26	20.44	27.24	22.46	24.91	28.72	26.72	27.70	37.81

有效成分 Effective component	100×		150×		200×
有效成分 Effective component	载药量 Drug loading/(g·m^-3)	固着率 Fixation rate(%)	载药量 Drug loading/(g·m^-3)	固着率 Fixation rate(%)	载药量 Drug loading/(g·m^-3)	固着率 Fixation rate(%)
丙环唑Pro.	333.1	95.7	227.6	94.8	167.0	93.0
BIT	333.1	90.1	227.6	87.1	167.0	81.2
高效氯氟氰菊酯Cyh.	66.2	95.8	45.5	93.9	33.4	91.6
总计/平均Total/mean	732.4	93.9	500.7	91.9	367.4	88.6

处理编号 Serial number	白腐菌Coriolus versicolor		褐腐菌Gloeophyllum trabeum
处理编号 Serial number	载药量Drug loading/(g·m^-3)	质量损失率 Mass loss rate(%)	载药量Drug loading/(g·m^-3)	质量损失率 Mass loss rate(%)
杨木对照Poplar contrast	—	76.8	—	33.1
处理1 Sample 1	153.6+7.7	3.0	161.6+8.1	2.2
处理2 Sample 2	200.0+10.0	4.8	221.1+11.1	2.2
处理3 Sample 3	250.7+12.5	1.7	274.8+13.7	2.4

Preparation and Effect Evaluation of Organic Preservative for Ancient Buildings Wood Biodeterioration

RichHTML

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

Figures/Tables 11

References 0

Related Articles 9

Recommended Articles

Metrics

Comments

处理方式 Treatment	A₁			A₂			A₃
处理方式 Treatment	L^*	a^*	b^*	L^*	a^*	b^*	L^*	a^*	b^*
处理前Before treatment	69.34	5.80	26.62	70.01	4.50	25.07	69.04	1.78	19.57
处理后After treatment	67.73	6.48	25.99	70.48	5.07	25.60	72.01	2.32	20.59
ΔE^*			1.86			0.91			3.19

稀释倍数 Dilution times	载药量 Drug loading/(g·m^-3)	试样完好程度Soundness
稀释倍数 Dilution times	载药量 Drug loading/(g·m^-3)	腐朽完好值Anti-corrosion performance	白蚁蛀蚀完好值Anti-termite performance
CK	0	9.5	5.8
667	128.3+6.5	10	10
500	149.3+7.6	10	10
400	204.4+10.4	10	10

[1]	Xingxia Ma,Lin Wang,Haiyan Zhu,Bo Liu,Bin Zhang,Yun Lu,Yanhua Wang,Mingliang Jiang,Liuru Wang. Risk Zones of Carpenter Bees for Wooden Structure of Ancient Buildings in China [J]. Scientia Silvae Sinicae, 2021, 57(4): 116-123.
[2]	Li Xiaowen, Xi Lixia, Jiang Mingliang. The Leachability of Five Kinds of Triazoles and Their Copper Triazole Formulations [J]. Scientia Silvae Sinicae, 2017, 53(3): 147-153.
[3]	Shi Yapan, Chi Yujie, Yu Cun, Han Shuying. Decoloring Conditions to Congon Red by Irpex lacteus CB1 [J]. Scientia Silvae Sinicae, 2016, 52(8): 115-121.
[4]	Ma Xingxia, Jiang Mingliang, Wang Jieying. The Climate Change Effects on Boundaries of Wood Decay and Termite Hazard Zones in China [J]. Scientia Silvae Sinicae, 2015, 51(11): 83-90.
[5]	Xi Lixia, Ma Xingxia, Jiang Mingliang. Decay and Termite Resistant Performance of Triazole Preservatives [J]. Scientia Silvae Sinicae, 2013, 49(7): 123-128.
[6]	Ma Xingxia;Jiang Mingliang;Qin Daochun. Macro- and Micro-Structural Changes in Bamboo after Attack by Various Fungi [J]. Scientia Silvae Sinicae, 2012, 48(11): 76-82.
[7]	Li Xiaowen;Li Min;Qin Shaoshan;Li Jianing;Lin Weifu. Biological Durability of Heat-Treated Rubber Wood [J]. Scientia Silvae Sinicae, 2012, 48(4): 108-112.
[8]	Ma Xingxia;Wang Jieying;Jiang Mingling;Li Xiaoying. Biological Hazard Classifications and Hazard Map Development for Terrestrial Applications of Wood in China [J]. Scientia Silvae Sinicae, 2011, 47(12): 129-135.
[9]	Huang Suyong;Li Kaifu;She Xiangwei. Antibacterial Property of China Fir/TiO₂ Composite [J]. Scientia Silvae Sinicae, 2011, 47(1): 181-184.