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›› 1984, Vol. 20 ›› Issue (1): 57-65.

• 论文及研究报告 • 上一篇    下一篇

两种落叶松木材中阿拉伯半乳聚糖的含量、分子性质及对水泥固化作用的影响

徐鹿鹿   

  1. 中国林业科学研究院木材工业研究所
  • 收稿日期:1900-01-01 修回日期:1900-01-01 出版日期:1984-02-25 发布日期:1984-02-25

STUDIES ON ARABINOGALACTAN FROM LARCH TIMBERS GROWN IN NORTHEASTERN CHINA——CONTENTS, MOLECULAR PROPERTIES AND EFFECTS ON SETTING OF CEMENT

Xu Lulu   

  1. Institute of Wood Industry, Chinese Academy of Forestry
  • Received:1900-01-01 Revised:1900-01-01 Online:1984-02-25 Published:1984-02-25

摘要: 为了从化学方面探讨落叶松水泥刨花板生产中存在的缓凝等问题,对落叶松(Larix gmelini)和黄花落叶松(L. olgensis)阿拉伯半乳聚糖进行了分离和鉴定,并测得其在木材中的含量分别为7.0%和10.2%;分子量分别为53000和44000;糖基组成相同,均有阿拉伯糖基、半乳糖基和两种糖醛酸基,其中半乳糖与阿拉伯糖的分子比约为6:1。扫描电镜和差热分析研究表明,落叶松阿拉伯半乳聚搪对水泥的水化结晶过程有严重的不良影响,它能延缓水泥的凝结并降低水泥固化的强度。

Abstract: The arabinogalactans from Larix gmekini and L. olgensis are isolated and characterized, correspondingly, the cotents are 7% and 10.2%, the molecular weights (MW) are 53000 and 44000, respectively. Both species are resemble each other in sugar composition which includes galactose, arabinose and uronic residues, and the ratio of galactose to arabinose is approximately 6. The results of SEM and DTA show that the effect of arabinogalactan on hydration and crystallization of Portland cement is seriously harmful. It is an inhibitor of setting and hardening of Portland cement.