Scientia Silvae Sinicae ›› 2012, Vol. 48 ›› Issue (8): 123-128.doi: 10.11707/j.1001-7488.20120820
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Liu Hongjun, Tan Weihong, Zhou Yonghong, Zhang Meng
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Abstract:
The decomposition reaction and mechanism of abietic acid with the purity 99.32% was tested by thermogravimetric analysis (TG),differential scanning calorimetry (DSC) and thermogravimetric analyzer coupled to a quadrupole mass spectrometer (TG-MS). The thermal decomposition activation energy of abietic acid at 20%(TG), 40%(TG), 60%(TG) were 12.76, 12.96, 11.81 kJ·mol-1, respectively. The results of TG-MS showed that there are micromolecules, whose m/z are between 40 to 90 when decomposed after 362.2 ℃, which proved that the decomposition process of abietic acid is first off isopropyl, carboxyl, and then open-ring. The fusion heat, heat of gasification, heat capacity of solid state, liquid state and phase change form solid to liquid were 49.3 J·g-1, 2 096.4 J·g-1, 1.469 J·g-1K-1, 1.163 J·g-1K-1 and 4.769 J·g-1K-1, respectively.
Key words: abietic acid, thermal analysis, thermal decomposition kinetics, heat capacity
CLC Number:
TQ351.47+1
Liu Hongjun;Tan Weihong;Zhou Yonghong;Zhang Meng. Thermal Decomposition Reaction of Abietic Acid[J]. Scientia Silvae Sinicae, 2012, 48(8): 123-128.
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URL: http://www.linyekexue.net/EN/10.11707/j.1001-7488.20120820
http://www.linyekexue.net/EN/Y2012/V48/I8/123