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›› 1980, Vol. 16 ›› Issue (3): 214-220.

• 论文及研究报告 • 上一篇    下一篇

中国松香、松节油主要化学组成的研究

粟子安 梁志勤 秦文龙 姜紫荣   

  1. 中国林业科学研究院林产化工研究所
  • 收稿日期:1900-01-01 修回日期:1900-01-01 出版日期:1980-08-25 发布日期:1980-08-25

STUDY ON THE PRINCIPAL CHEMICAL CONSTITUENTS OF CHINESE ROSIN AND TURPENTINE

Su Zi-an,Liang Zhi-qin,Qin Wen-long,Jiang Zi-rong   

  1. Research Institute for Chemical Processing of Forest Products, Chinese Academy of Forestry
  • Received:1900-01-01 Revised:1900-01-01 Online:1980-08-25 Published:1980-08-25

Abstract: Samples of turpentine and rosin from six species of pine Grown in different regions of China, have been Collected and analysed by gas chromatography. Turpentine from Pinus massoniana consists mainly of α-pinene and β-pinene, which representing over 90% of the total. This is also the case of turpentine from Pinus yunnanesis. The turpentine from Pinus elliottii contains β-pinene as high as 39.4%. The α-pinene contained in turpentines from both Pinus langbianensis and Pinus finlaysonlana is dextrorotatory. Pinus langbianensis turpentine has the highest α-pinene content amongst the samples tested while turpentine from Pinus armand contains more β-pinene (15.1%). Rosin from Pinus massoniana contains 76-86% resin acids of abietic type. There seems no distinct relationship between chemical constitution of rosin and the locality of tree growth, but on the other hand, some characteristic features in the composition of rosin of different origin do exist. for instance, Pinus elliottii rosin contains more than 20% iso-pimaric acid and about 9% dehydroabietic acid. rosin from Pinus finlaysonlana contains 18.5% dibasic acids with higher iso-pimaric acid content and no pimaric acid. The content of abietic type resin acids in this rosin is the lowest (53.2%) in compare with the others. The composition of resin acids in rosins from both Pinus langbianensis and Pinus yunnanesis is similar to that in Pinus massoniana, Pinus armandi rosin contains resinacids of abietic type as high as 90% but with no dehydroabietic acid presenting. The rather evident differences in chemical composition of turpentine and resin acid constitution of rosin between samples from different specice of pine might give us some genetic informations of the trees.